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Novel fatty acid esters of (7 E , 12 E , 18 R , 20 Z )-variabilin from the marine sponge Ircinia felix

Novel fatty acid esters of (7 E , 12 E , 18 R , 20 Z )-variabilin from the marine sponge Ircinia felix The methanolic extract of the marine sponge Ircinia felix has yielded nine novel fatty acid esters, (7 E , 12 E , 18 R , 20 Z )-variabilin (5 Z , 9 Z )-22-methyltricosadienoate, (7 E , 12 E , 18 R , 20 Z )-variabilin (5 Z , 9 Z )-tetracosadienoate, (7 E , 12 E , 18 R , 20 Z )-variabilin hexadecanoate, (7 E , 12 E , 18 R , 20 Z )-variabilin 10-methylhexadecanoate, (7 E , 12 E , 18 R , 20 Z )-variabilin 15-methylhexadecanoate, (7 E , 12 E , 18 R , 20 Z )-variabilin 14-methylhexadecanoate, (7 E , 12 E , 18 R , 20 Z )-variabilin 9-octadecenoate, (7 E , 12 E , 18 R , 20 Z )-variabilin octadecanoate, and (7 E , 12 E , 18 R , 20 Z )-variabilin 2,11-dimethyloctadecanoate, along with the recently described (7 E , 12 E , 18 R , 20 Z )-variabilin 11-methyloctadecanoate. The characterization of the new fatty acids (5 Z , 9 Z )-22-methyltricosadienoic and 2,11-dimethyloctadecanoic acids is also described. The chemical structures were determined by extensive spectroscopic, chromatographic, and chemical analyses. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Lipids Springer Journals
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