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Manipulation of the heme electronic structure by external stimuli and ligand field

Manipulation of the heme electronic structure by external stimuli and ligand field This review describes the switching behaviors of the electronic structure, which were observed in iron(III) porphyrinoids, by the addition of external stimuli. The combined analysis by various methods, such as EPR, Mössbauer, SQUID, single crystal X-ray structure analysis, revealed a wide variety of electronic structures of the heme related complexes. This paper focuses in particular on the spin-crossover phenomenon in the solid state. An overview of spin-crossover phenomena found in iron(III) porphyrinoids between (i) S = 5/2 and S = 1/2, (ii) S = 3/2 and S = 1/2, (iii) S = 5/2 and S = 3/2, will be described. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Hyperfine Interactions Springer Journals

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References (5)

Publisher
Springer Journals
Copyright
Copyright © 2011 by Springer Science+Business Media B.V.
Subject
Physics; Condensed Matter Physics; Nuclear Physics, Heavy Ions, Hadrons; Surfaces and Interfaces, Thin Films; Atomic, Molecular, Optical and Plasma Physics
ISSN
0304-3843
eISSN
1572-9540
DOI
10.1007/s10751-011-0499-x
Publisher site
See Article on Publisher Site

Abstract

This review describes the switching behaviors of the electronic structure, which were observed in iron(III) porphyrinoids, by the addition of external stimuli. The combined analysis by various methods, such as EPR, Mössbauer, SQUID, single crystal X-ray structure analysis, revealed a wide variety of electronic structures of the heme related complexes. This paper focuses in particular on the spin-crossover phenomenon in the solid state. An overview of spin-crossover phenomena found in iron(III) porphyrinoids between (i) S = 5/2 and S = 1/2, (ii) S = 3/2 and S = 1/2, (iii) S = 5/2 and S = 3/2, will be described.

Journal

Hyperfine InteractionsSpringer Journals

Published: Dec 7, 2011

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