Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Kinetics and mechanism of stripping of Pu(IV) by N , N -dimethylhydroxylamine using a Lewis cell

Kinetics and mechanism of stripping of Pu(IV) by N , N -dimethylhydroxylamine using a Lewis cell The kinetics of back-extraction of Pu(IV) from 30% Tri-Butyl-Phosphate/Odourless Kerosene (TBP/OK) into a nitric acid solution containing N , N -dimethylhydroxylamine (DMHAN) have been investigated using a Lewis cell. The different parameters affecting the back-extraction rate of Pu(IV) such as plutonium, nitric acid, DMHAN concentration in addition to temperature, stirring speed were separately studied and a rate equation was deduced. The activation energy of this process is 28.4 kJ/mol. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Radioanalytical and Nuclear Chemistry Springer Journals

Kinetics and mechanism of stripping of Pu(IV) by N , N -dimethylhydroxylamine using a Lewis cell

Loading next page...
 
/lp/springer-journals/kinetics-and-mechanism-of-stripping-of-pu-iv-by-n-n-1tOQBUvhSN

References (9)

Publisher
Springer Journals
Copyright
Copyright © 2010 by Akadémiai Kiadó, Budapest, Hungary
Subject
Chemistry; Inorganic Chemistry ; Diagnostic Radiology; Nuclear Physics, Heavy Ions, Hadrons; Physical Chemistry ; Nuclear Chemistry
ISSN
0236-5731
eISSN
1588-2780
DOI
10.1007/s10967-009-0371-5
Publisher site
See Article on Publisher Site

Abstract

The kinetics of back-extraction of Pu(IV) from 30% Tri-Butyl-Phosphate/Odourless Kerosene (TBP/OK) into a nitric acid solution containing N , N -dimethylhydroxylamine (DMHAN) have been investigated using a Lewis cell. The different parameters affecting the back-extraction rate of Pu(IV) such as plutonium, nitric acid, DMHAN concentration in addition to temperature, stirring speed were separately studied and a rate equation was deduced. The activation energy of this process is 28.4 kJ/mol.

Journal

Journal of Radioanalytical and Nuclear ChemistrySpringer Journals

Published: Feb 1, 2010

There are no references for this article.