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The Fe-doped near-stoichiometric LiNbO3 crystal has been grown from the Li-rich melt by Czochralski method. The UV-Vis absorption spectra, IR transmittance spectra and X-ray diffraction were measured and used to study the defect structure of the crystal. Compared with that of congruent Fe:LiNbO3, in near-stoichiometric Fe:LiNbO3, the lattice parameter reduces, the basal absorption edge shifts towards shorter wavelength, and the OH stretching vibration absorption band shifts towards the lower wavenumber side (3466 cm−1) in the Fe-doped near-stoichiometric LiNbO3.
Journal of Materials Science – Springer Journals
Published: Oct 9, 2004
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