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- Publisher
- Springer Journals
- Copyright
- Copyright © 2006 by Springer-Verlag
- Subject
- Chemistry; Polymer Sciences; Soft and Granular Matter, Complex Fluids and Microfluidics; Characterization and Evaluation of Materials; Physical Chemistry; Food Science; Nanotechnology and Microengineering
- ISSN
- 0303-402X
- eISSN
- 1435-1536
- DOI
- 10.1007/s00396-006-1513-8
- Publisher site
- See Article on Publisher Site
Abstract
Water absorption, surface energetic, and friction coefficient of filled silicone rubber composites containing different amounts of a superadsorbent hydrogel, poly(acrylic acid) (PAA), were investigated. Measurements were performed in two different time windows, 1 and 5 weeks, to study the effect of hydration time on surface polarity of the samples. It was shown that water absorption increased consistently with hydrogel content and that prolongation of hydration time led to a marked increase in surface tension and polarity. Friction, as measured by a solid–solid contact method in phosphate buffer saline, showed strong dependence on polarity of the composite surface. Results demonstrate that the surface of the composite continued to evolve after the bulk had reached equilibrium swelling and the surface tension reached that of PAA after 5 weeks of hydration time.
Journal
Colloid Polymer Science – Springer Journals
Published: May 24, 2006