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C. Serna, J. Ahlrichs, J. Serratosa (1975)
Sepiolite Anhydride and Crystal FoldingClays and Clay Minerals, 23
R. Frost, Kristy Erickson (2004)
Thermal decomposition of natural iowaiteJournal of Thermal Analysis and Calorimetry, 78
S. Yariv (1990)
Combined DTA — mass spectrometry of organo-clay complexesJournal of thermal analysis, 36
Y. Xi, W. Martens, H. He, R. Frost (2005)
Thermogravimetric analysis of organoclays intercalated with the surfactant octadecyltrimethylammonium bromideJournal of Thermal Analysis and Calorimetry, 81
R. Frost, M. Weier, Kristy Erickson (2004)
Thermal decomposition of struviteJournal of Thermal Analysis and Calorimetry, 76
R. Frost, J. Kristóf, E. Horváth, J. Kloprogge (2001)
Separation of Adsorbed Formamide and Intercalated Formamide Using Controlled Rate Thermal Analysis MethodologyLangmuir, 17
R. Frost, R. Wills, J. Kloprogge, W. Martens (2006)
Thermal decomposition of ammonium jarosite (NH4)Fe3(SO4)2(OH)6Journal of Thermal Analysis and Calorimetry, 84
R. Frost, Z. Ding (2003)
Controlled rate thermal analysis and differential scanning calorimetry of sepiolites and palygorskitesThermochimica Acta, 397
R. Frost, J. Kristóf, Z. Ding, E. Horváth (2003)
Controlled Rate Thermal Analysis of Formamide Intercalated Kaolinites
R. Frost, W. Martens, M. Adebajo (2005)
Synthesis of the mixed oxide catalysts based upon the nickel-copper hydrotalcites of the type NixCu6-xCr2(OH)16(CO3)×4H2OJournal of Thermal Analysis and Calorimetry, 81
H. Hayashi, R. Otsuka, N. Imai (1969)
Infrared study of sepiolite and paly-gorskite on heatingAmerican Mineralogist, 54
A. Musumeci, G. Silva, W. Martens, E. Waclawik, R. Frost (2007)
Thermal decomposition and electron microscopy studies of single-walled carbon nanotubesJournal of Thermal Analysis and Calorimetry, 88
(1974)
Study of sepiolite with the aid of data from electronic microscopy
M. Murât, J. Gielly (1969)
Observations expérimentales relatives à l'étude des réactions de déshydratation et de déshydroxylation des minéraux argileux par mesures de conductivité électrique et analyse thermique, 21
R. Frost, J. Kristóf, E. Horváth, J. Kloprogge (2001)
The Modification of Hydroxyl Surfaces of Formamide-Intercalated Kaolinites Synthesized by Controlled Rate Thermal Analysis.Journal of colloid and interface science, 239 1
Aramendía, Boráu, Corredor, Jiménez, Marinas, Ruiz, Urbano (2000)
Characterization of the Structure and Catalytic Activity of Pt/Sepiolite Catalysts.Journal of colloid and interface science, 227 2
良一 木下, 裕 市村, 潤 小野寺, 典康 新村, 要二 仲山, 哲夫 樋口 (1998)
TG/DTA-MS測定条件の最適化と材料分析への応用Journal of the Mass Spectrometry Society of Japan, 46
(1955)
New types of clay minerals with long spacings at about 30 A
R. Frost, M. Weier (2004)
Thermal decomposition of humboldtine: A high resolution thermogravimetric and hot stage Raman spectroscopic studyJournal of Thermal Analysis and Calorimetry, 75
C. Serna, G. Vanscoyoc, J. Ahlrichs (1977)
Hydroxyl groups and water in palygorskiteAmerican Mineralogist, 62
Carlos Serna, J. Ahlrichs, J. Serratosa (1975)
Folding in Sepiolite CrystalsClays and Clay Minerals, 23
(1973)
Studies of pore structure of various solids by nitrogen adsorption. I. Natural sepiolites activated by hydrochloric acid
M. Brigatti, G. Franchini, L. Medici, L. Poppi, A. Stewart (1998)
Behaviour of sepiolite in Co2+ Cu2+ and Cd2+ removal from a simulated pollutant solutionAnnali Di Chimica, 88
R. Frost, Kristy Erickson, M. Weier (2004)
Thermal treatment of moolooiteJournal of Thermal Analysis and Calorimetry, 77
S. Palmer, J. Kristóf, V. Vágvölgyi, E. Horváth, R. Frost (2009)
Thermal decomposition of hydrotalcite with hexacyanoferrate(II) and hexacyanoferrate(III) anions in the interlayerJournal of Thermal Analysis and Calorimetry, 96
(1969)
Reactions of dehydration and dehydroxylation of clay minerals studies by electric conductivity measurements and differential thermal analysis
R. Frost, M. Weier, W. Martens (2005)
Thermal decomposition of jarosites of potassium, sodium and leadJournal of Thermal Analysis and Calorimetry, 82
E. Horváth, J. Kristóf, R. Frost, N. Heider, V. Vágvölgyi (2004)
Investigation of IrO2/SnO2 thin film evolution by thermoanalytical and spectroscopic methodsJournal of Thermal Analysis and Calorimetry, 78
R. Frost, Z. Ding, Huada Ruan (2003)
Thermal analysis of goethiteJournal of Thermal Analysis and Calorimetry, 71
Jocelyne Bouzaid, R. Frost, W. Martens (2007)
Thermal decomposition of the composite hydrotalcites of iowaite and woodalliteJournal of Thermal Analysis and Calorimetry, 89
R. Frost, M. Weier, W. Martens (2005)
Thermal decomposition of liebigiteJournal of Thermal Analysis and Calorimetry, 82
S. Yariv, I. Lapides (2000)
The Effect of Mechanochemical Treatments on Clay Minerals and the Mechanochemical Adsorption of Organic Materials onto Clay MineralsJournal of Materials Synthesis and Processing, 8
R. Frost, Kristy Erickson (2004)
Thermal decomposition of synthetic hydrotalcites reevesite and pyroauriteJournal of Thermal Analysis and Calorimetry, 76
J. Pérez-Rodríguez, E. Galán (1994)
Determination of impurity in sepiolite by thermal analysisJournal of thermal analysis, 42
H. Nagata (1977)
Thermal Analysis of Sepiolite by means of DSCJournal of the Clay Science Society of Japan, 17
Fibrant Segal
A CHARACTERIZATION OF
R. Frost, J. Kristóf, W. Martens, M. Weier, E. Horváth (2006)
Erratum to Thermal decomposition of sabugaliteJournal of Thermal Analysis and Calorimetry, 83
R. Frost, J. Kristóf, E. Horváth, W. Martens, J. Kloprogge (2002)
Complexity of intercalation of hydrazine into kaolinite--a controlled rate thermal analysis and DRIFT spectroscopic study.Journal of colloid and interface science, 251 2
E. Horváth, J. Kristóf, R. Frost, A. Redey, V. Vágvölgyi, T. Cseh (2003)
Hydrazine-hydrate intercalated halloysite under controlled-rate thermal analysis conditionsJournal of Thermal Analysis and Calorimetry, 71
(1964)
The thermal behavior of sepiolite
(1947)
The application of differential thermal analysis to the study of the clay minerals found in soils
Carlos Serna, M. Rautureau, R. Prost, C. Tchoubar, J. Serratosa (1974)
Etude de la sépiolite à l'aide des données de la microscopie électronique, de l'analyse thermopondérale et de la spectroscopie infrarouge, 26
R. Frost, J. Kristóf, W. Martens, M. Weier, E. Horváth (2006)
THERMAL DECOMPOSITION OF SABUGALITE A controlled rate thermal analysis studyJournal of Thermal Analysis and Calorimetry, 83
R. Frost, W. Martens, Z. Ding, J. Kloprogge (2003)
DSC and high-resolution TG of synthesized hydrotalcites of Mg and ZnJournal of Thermal Analysis and Calorimetry, 71
Z. Ding, R. Frost (2002)
Controlled rate thermal analysis of nontroniteThermochimica Acta, 389
S. Cebulak, A. Langier-Kuźniarowa (1998)
Some Remarks on the Methodology of Thermal Analysis of Clay MineralsJournal of Thermal Analysis and Calorimetry, 53
R. Frost, J. Kristóf, M. Weier, W. Martens, E. Horváth (2005)
Thermal decomposition of metatorbernite - a controlled rate thermal analysis studyJournal of Thermal Analysis and Calorimetry, 79
Jocelyne Bouzaid, R. Frost (2007)
Thermal decomposition of stichtiteJournal of Thermal Analysis and Calorimetry, 89
J. Kristóf, Ray Frost, J. Kloprogge, E. Horváth, É. Makó (2002)
Detection of four different OH-groups in ground kaolinite with controlled-rate thermal analysisJournal of Thermal Analysis and Calorimetry, 69
Yu-Hsiang Lin, M. Adebajo, R. Frost, J. Kloprogge (2005)
Thermogravimetric analysis of hydrotalcites based on the takovite formula NixZn6-xAl2(OH)16(CO3)·4H2OJournal of Thermal Analysis and Calorimetry, 81
(1998)
The optimization of the TG/DTA-MS measurements and the application for the material analysis
M. Vicente, M. Suárez, J. Lopez-Gonzalez, M. Bañares-Muñoz (1996)
Characterization, Surface Area, and Porosity Analyses of the Solids Obtained by Acid Leaching of a SaponiteLangmuir, 12
R. Frost, A. Musumeci, M. Adebajo, W. Martens (2007)
Using thermally activated hydrotalcite for the uptake of phosphate from aqueous mediaJournal of Thermal Analysis and Calorimetry, 89
C. Serna, G. Vanscoyoc, J. Ahlrichs (1976)
Uncoupled water found in palygorskiteJournal of Chemical Physics, 65
Controlled rate thermal analysis (CRTA) technology offers better resolution and a more detailed interpretation of the decomposition processes of a clay mineral such as sepiolite via approaching equilibrium conditions of decomposition through the elimination of the slow transfer of heat to the sample as a controlling parameter on the process of decomposition. Constant-rate decomposition processes of non-isothermal nature reveal changes in the sepiolite as the sepiolite is converted to an anhydride. In the dynamic experiment two dehydration steps are observed over the ~20–170 and 170–350 °C temperature range. In the dynamic experiment three dehydroxylation steps are observed over the temperature ranges 201–337, 337–638 and 638–982 °C. The CRTA technology enables the separation of the thermal decomposition steps.
Journal of Thermal Analysis and Calorimetry – Springer Journals
Published: Dec 1, 2009
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