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T. Brill, P. Gongwer, G. Williams (1994)
Thermal Decomposition of Energetic Materials. 66. Kinetic Compensation Effects in HMX, RDX, and NTOThe Journal of Physical Chemistry, 98
N. Koga, Haruhiko Tanaka (1988)
Significance of kinetic compensation effect in the thermal decomposition of a solidThermochimica Acta, 135
R. Agrawal (1988)
The compensation effectJournal of thermal analysis, 34
W. Ernst (1985)
False compensation effect in studies of kinetics of cure by differential scanning calorimetryThermochimica Acta, 91
L. Cafferata, G. Eyler, E. Svartman, A. Cañizo, E. Alvarez (1991)
Solvent effects in the thermal decomposition reactions of cyclic ketone diperoxidesJournal of Organic Chemistry, 56
V. Logvinenko, B. Peshchevitsky, O. Gegola (1980)
An analysis of the possible causes of apparent compensation effects when investigating a substance under varying experimental conditionsJournal of thermal analysis, 18
R. Agrawal (1989)
The compensation effect: A fact or a fictionJournal of thermal analysis, 35
V. Logvinenko, L. Myachina (1980)
A study of the dehydratation kinetics of binuclear EDTA chelates CaML · nH2OJournal of thermal analysis, 19
W. Chew, D. Harpp (1993)
Thermal decomposition of 3',3'-dichlorospiro[fluorene-9,2'-thiirane]: kinetics and mechanismJournal of Organic Chemistry, 58
Y. Inoue, N. Yamasaki, Taizo Yokoyama, A. Tai (1992)
Enantiodifferentiating Z-E photoisomerization of cyclooctene sensitized by chiral polyalkyl benzenepolycarboxylatesJournal of Organic Chemistry, 57
O. Nikulicheva, V. Fadeeva, V. Logvinenko (1996)
Calculation of the kinetic parametersJournal of thermal analysis, 47
Y. Matsumoto, R. Ueoka (1990)
Studies on thermodynamics for hydrolysis. 3. Isokinetic temperature related to molecular location of reactants in coaggregatesJournal of Organic Chemistry, 55
This paper reports a linear relationship between kinetic characteristics from the Arrhenius equation describing a decomposition process found when studying the kinetics of thermolysis of spatially hindered phenols. This relationship between the coefficients is known in the literature as a 'compensation effect'. The existence of the compensation effect permits some conclusions concerning the decomposition mechanism and thermal characteristics of the compounds under investigation.
Journal of Thermal Analysis and Calorimetry – Springer Journals
Published: Jan 1, 1999
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