The structures of alkalides and electrides. IV. Structure of Li+(tmtcy)Li+(dmtcy)-.CH3NH2Na-
Abstract
<h2>Acta Crystallographica Section C</h2><h3>Crystal Structure Communications</h3><h3>0108-2701</h3> <h2>research papers (metal-organic compounds)</h2> Volume 46 Part 10 Pages 1835-1837 October 1990 <h2>The structures of alkalides and electrides. IV. Structure of Li + (tmtcy)[Li + (dmtcy) - .CH 3 NH 2 ]Na - </h2> R. H. Huang, D. L. Ward and J. L. Dye Acta Cryst. (1990). C46, 1835-1837 The Structures of Alkalides and Electrides. IV. Structure of Li + (tmtcy*)- [Li + (dmtcyt)-.CH3NH2]Na- BY RuI H. HUANG,~ DONALD L. WARD AND JAMES L. DYE Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, Michigan 48824, USA (Received 7 June 1989; accepted 15 January 1990) Abstract. /z-(1,4-Dimethyl- 1,4,7-triazacyclononami- do)(methylamine)(1,4,7-trimethyl-l,4,7-triazacyclo- nonane)dilithium natride, [Li2(CsH~sN3)(CHsN)- (C9H21N3)] +.Na-, Mr = 395"47, orthorhombic, Pbca, a 25.27 8), b = 10.904 (3), c = 21.566 (6) V = 5942.1 (7) A Z = 8, Dx = 0-884 g cm- ,t(Mo Ka) = 0.71073 .~, ~ = 0"6 cm- 1, f(000) = 1744, T = 203 (4) K, final R = 0-078 for 650 [I > * tmtcy: 1,4,7-trimethyl- 1,4,7-triazacyclononane. t dmtcy: 1,4-dimethyl- 1,4,7-triazacyclononane. :~ To whom correspondence should be addressed. 0108-2701/90/101835-03503.00 3tr(/)] of 2779 unique reflections. The structure con- tains a mixed unit