The structure of trans-dichlorobis(+)-(S,S)-trans-1,2-diaminocyclopentanecobalt(III) chloride hydrochloride dihydrate, trans-CoCl2{(+)-cptn}2Cl.HCl.2H2O
Abstract
<h2>Acta Crystallographica Section B</h2><h3>Structural Crystallography and Crystal Chemistry</h3><h3>0567-7408</h3> <h2>research papers</h2> Volume 37 Part 6 Pages 1189-1193 June 1981 <h2>The structure of trans -dichlorobis[(+)-( S , S )- trans -1,2-diaminocyclopentane]cobalt(III) chloride hydrochloride dihydrate, trans -[CoCl 2 {(+)-cptn} 2 ]Cl.HCl.2H 2 O</h2> M. Goto, K. Ohta, K. Toriumi and T. Ito Acta Cryst. (1981). B37, 1189-1193 The Structure of trans-Diehlorobis[(+)-( S,S)-trans- 1,2-diaminoeyelopentane]eobalt(III) Chloride Hydroehloride Dihydrate, trans-[CoCl2 { (+)-eptn } 2]Cl. HCI. 2H20 By MASAFUMI GOTO AND KYOKO OrrrA Faculty of Pharmaceutical Sciences, Nagoya City University, Mizuho-ku, Nagoya 467, Japan AND KOSHIRO TORIUMI AND TASUKU ITO Institute for Molecular Science, Okazaki 444, Japan (Received 5 November 1980; accepted 8 December 1980) Abstract Crystals of the title compound, [Co(CsHx2N2)2C12]Ct.- HCI.2H20, Mr = 438.11, are orthorhombic, space group P22~21, with a = 9.571 (2), b = 24.541 (3), c = 8.412 (2)/~,U= 1975.9 (7)/k3, Z = 4, Dx = 1.47, 0567-7408/81/061189-05501.00 Dm = 1.47 Mg m-a, g(Mo Ka) = 1.446 mm-1. The crystal structure has been refined to give an R value of 0.044 for 2666 observed reflections collected by X-ray diffractometry. The complex cation has approximate D2 symmetry, the Co atom being surrounded pseudo- octahedrally by the four N atoms of two