The monoclinic phase Au2(C25H22P2)2Cl2.2CH3CN
Abstract
<h2>Acta Crystallographica Section C</h2><h3>Crystal Structure Communications</h3><h3>0108-2701</h3> <h2>metal-organic compounds</h2> Volume 50 Part 4 Pages 538-540 April 1994 <h2>The monoclinic phase [Au 2 (C 25 H 22 P 2 ) 2 ]Cl 2 .2CH 3 CN</h2> L.-S. Liou, C.-P. Liu and J.-C. Wang Acta Cryst. (1994). C50, 538-540 The Monoclinic Phase IAu2(C2sI-I22P2)21CI2.2CH3CN LrN-SHu Llou, CHAO-PEI LIU AND Ju-CmTN WANG* Department of Chemistry, Soochow University, Taipei, Taiwan 11102 c" Cl CI6 05 C21 CII C12 t,~;) c~3 C14 C26 C24 C25 (Received 22 March 1993; accepted 1 September 1993) Abstract Bis[/z-bis(diphenylphosphino)methane-P,P']digold(I) dichloride bis(acetonitrile) solvate, [Au2(C25Hz2- P2)2]C12.2CH3CN, crystallized in the monoclinic system. A crystallographic inversion centre lies at the © 1994 International Union of Crystallography Printed in Great Britain - all rights reserved Fig. 1. Molecular drawing of the title compound with 50% probability displacement ellipsoids for the non-H atoms. Acta Crystallographica Section C ISSN 0108-2701 ©1994 L.-S. LIOU, C.-P. LIU AND J.-C. WANG 539 Wohlleben, Schubert, Frank & Huttner, 1977). In this paper, we report a monoclinic phase crystal structure (space group P2~/c) of [Au(dppm)C1]2, (I), solvated with CH3CN. The molecular structure is L° CI"" [ similar to the triclinic structure. The only significant difference between the two structures is the