Structures of aqua and pyridine adducts of dimeric copper(II) 2-chlorobenzoate
Abstract
<h2>Acta Crystallographica Section C</h2><h3>Crystal Structure Communications</h3><h3>0108-2701</h3> <h2>research papers (metal-organic compounds)</h2> Volume 48 Part 9 Pages 1590-1594 September 1992 <h2>Structures of aqua and pyridine adducts of dimeric copper(II) 2-chlorobenzoate</h2> T. Kawata, S. Ohba, T. Tokii, Y. Muto and M. Kato Acta Cryst. (1992). C48, 1590-1594 Structures of Aqua and Pyridine Adducts of Dimeric Copper(ll) 2-Chlorobenzoate BY TAKASm KAWATA AND SmGERU OrmA* Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, Yokohama 223, Japan TADASHI TOKH AND YONEICHIRO MUTO Department of Chemistry, Faculty of Science and Engineering, Saga University, Saga 840, Japan AND MICHINOBU KATO Aichi Prefectural University, Mizuho-ku, Nagoya 467, Japan (Received 29 November 1991; accepted 27 January 1992) Abstract. Tetrakis(/z-2-chlorobenzoato-O,O')-bis- [aquacopper(II)], [Cu2(C7H4C102)4(H20)2], (I), Mr = 785.4, monoclinic, P21/n, a=7.214(2), b= 19.554 (4), c = 10.877 (4) A, fl = 103.82 (3)°, V= 1489.9 (7) A3, Z = 2, Dm= 1.75 (2), Dx = 1.75 Mg m-3, A(Mo Ka) = 0.71073 A, /z = 1.848 mm-1, F(000) = 788, T = 298 (2) K, R = 0.032 for 2536 observed reflections. Tetrakis(/z-2-chloro- benzoato-O,O')-bis[pyridinecopper(II)] di(tetra- chloromethane), [Cu2(C7H4C102)4(C5H5N)2].2CC14, (II), Mr = 1215.2, monoclinic, P2Ja, a = 23.365 (3), b = 10.688 (1), c = 20.542 (2) A,