Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Structure of pentapotassium dihydrogenhexamolybdoantimonate heptahydrate

Structure of pentapotassium dihydrogenhexamolybdoantimonate heptahydrate <h2>Acta Crystallographica Section C</h2><h3>Crystal Structure Communications</h3><h3>0108-2701</h3> <h2>research papers (inorganic compounds)</h2> Volume 44 Part 11 Pages 1879-1881 November 1988 <h2>Structure of pentapotassium dihydrogenhexamolybdoantimonate heptahydrate</h2> A. Ogawa, H. Yamato, U. Lee, H. Ichida, A. Kobayashi and Y. Sasaki Acta Cryst. (1988). C44, 1879-1881 Structure of Pentapotassium Dihydrogenhexamolybdoantimonate Heptahydrate By A. OGAWA,* H. YAMATO,t U. LEE,~- H. ICHIDA, A. KOBAYASHI AND Y. SASAKI Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Tokyo l 13, Japan (Received 15 April 1988; accepted 7 June 1988) 1879 Abstract. Ks[H2SbMo6024].7H20, Mr = 1405.1, monoclinic, P2~/a, a = 20.783 (4), b = 10.105 (1), c=15.085(2)A, fl=112.15(1)°, U=2934(1)A3, Z=4, D,,=3.20, Dx= 3.18 Mgm-3, 2(MoKct)= 0.71069/(, /1=4.16mm-1, F(000)=2648, T= 298 K, R =0.057 for 5889 unique reflections. The structure contains the discrete polyanion I H2SbMo6- O24]5-, the configuration of which differs from that of [TeMo602416- and [IMo602415-, but is identical to that of [Mo7024]6-. Two polyanion molecules are paired by hydrogen bonds, and the positions of the H atoms were estimated from anomalies in Mo-O distances. Introduction. We obtained four new heteropolyanions containing Sbv and MoVl: KsIH2SbMo60241.7H20, K6[ HESb6Mo4036].7H20, (NH4)7[ H 10SbsMosO36].- nHzO and K6[Hi2Sb4Mol0Os0].8H20; their crystal structures have been determined. SbVO6 coordination has been http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section C: Crystal Structure Communications International Union of Crystallography

Structure of pentapotassium dihydrogenhexamolybdoantimonate heptahydrate

Structure of pentapotassium dihydrogenhexamolybdoantimonate heptahydrate


Abstract

<h2>Acta Crystallographica Section C</h2><h3>Crystal Structure Communications</h3><h3>0108-2701</h3> <h2>research papers (inorganic compounds)</h2> Volume 44 Part 11 Pages 1879-1881 November 1988 <h2>Structure of pentapotassium dihydrogenhexamolybdoantimonate heptahydrate</h2> A. Ogawa, H. Yamato, U. Lee, H. Ichida, A. Kobayashi and Y. Sasaki Acta Cryst. (1988). C44, 1879-1881 Structure of Pentapotassium Dihydrogenhexamolybdoantimonate Heptahydrate By A. OGAWA,* H. YAMATO,t U. LEE,~- H. ICHIDA, A. KOBAYASHI AND Y. SASAKI Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Tokyo l 13, Japan (Received 15 April 1988; accepted 7 June 1988) 1879 Abstract. Ks[H2SbMo6024].7H20, Mr = 1405.1, monoclinic, P2~/a, a = 20.783 (4), b = 10.105 (1), c=15.085(2)A, fl=112.15(1)°, U=2934(1)A3, Z=4, D,,=3.20, Dx= 3.18 Mgm-3, 2(MoKct)= 0.71069/(, /1=4.16mm-1, F(000)=2648, T= 298 K, R =0.057 for 5889 unique reflections. The structure contains the discrete polyanion I H2SbMo6- O24]5-, the configuration of which differs from that of [TeMo602416- and [IMo602415-, but is identical to that of [Mo7024]6-. Two polyanion molecules are paired by hydrogen bonds, and the positions of the H atoms were estimated from anomalies in Mo-O distances. Introduction. We obtained four new heteropolyanions containing Sbv and MoVl: KsIH2SbMo60241.7H20, K6[ HESb6Mo4036].7H20, (NH4)7[ H 10SbsMosO36].- nHzO and K6[Hi2Sb4Mol0Os0].8H20; their crystal structures have been determined. SbVO6 coordination has been

Loading next page...
 
/lp/international-union-of-crystallography/structure-of-pentapotassium-dihydrogenhexamolybdoantimonate-uS6CqV270S

References (0)

References for this paper are not available at this time. We will be adding them shortly, thank you for your patience.

Publisher
International Union of Crystallography
Copyright
Copyright (c) 1988 International Union of Crystallography
ISSN
0108-2701
eISSN
1600-5759
DOI
10.1107/S0108270188007073
Publisher site
See Article on Publisher Site

Abstract

<h2>Acta Crystallographica Section C</h2><h3>Crystal Structure Communications</h3><h3>0108-2701</h3> <h2>research papers (inorganic compounds)</h2> Volume 44 Part 11 Pages 1879-1881 November 1988 <h2>Structure of pentapotassium dihydrogenhexamolybdoantimonate heptahydrate</h2> A. Ogawa, H. Yamato, U. Lee, H. Ichida, A. Kobayashi and Y. Sasaki Acta Cryst. (1988). C44, 1879-1881 Structure of Pentapotassium Dihydrogenhexamolybdoantimonate Heptahydrate By A. OGAWA,* H. YAMATO,t U. LEE,~- H. ICHIDA, A. KOBAYASHI AND Y. SASAKI Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Tokyo l 13, Japan (Received 15 April 1988; accepted 7 June 1988) 1879 Abstract. Ks[H2SbMo6024].7H20, Mr = 1405.1, monoclinic, P2~/a, a = 20.783 (4), b = 10.105 (1), c=15.085(2)A, fl=112.15(1)°, U=2934(1)A3, Z=4, D,,=3.20, Dx= 3.18 Mgm-3, 2(MoKct)= 0.71069/(, /1=4.16mm-1, F(000)=2648, T= 298 K, R =0.057 for 5889 unique reflections. The structure contains the discrete polyanion I H2SbMo6- O24]5-, the configuration of which differs from that of [TeMo602416- and [IMo602415-, but is identical to that of [Mo7024]6-. Two polyanion molecules are paired by hydrogen bonds, and the positions of the H atoms were estimated from anomalies in Mo-O distances. Introduction. We obtained four new heteropolyanions containing Sbv and MoVl: KsIH2SbMo60241.7H20, K6[ HESb6Mo4036].7H20, (NH4)7[ H 10SbsMosO36].- nHzO and K6[Hi2Sb4Mol0Os0].8H20; their crystal structures have been determined. SbVO6 coordination has been

Journal

Acta Crystallographica Section C: Crystal Structure CommunicationsInternational Union of Crystallography

Published: Nov 15, 1988

There are no references for this article.