Structure of a binuclear disulfido-vanadium complex, V2(-2-S2)2(Et2NCS2)4
Abstract
<h2>Acta Crystallographica Section C</h2><h3>Crystal Structure Communications</h3><h3>0108-2701</h3> <h2>research papers (metal-organic compounds)</h2> Volume 47 Part 10 Pages 2085-2087 October 1991 <h2>Structure of a binuclear disulfido-vanadium complex, [V 2 ( - 2 -S 2 ) 2 (Et 2 NCS 2 ) 4 ]</h2> Y. Yang, L. Huang, Q. Liu and B. Kang Acta Cryst. (1991). C47, 2085-2087 Structure of a Binuclear Disulfido-Vanadium Complex, [V2(/L-~2-S2)2(Et2NCS2)4] BY Yu YANG,* LIANGREN HUANG, QIUTIAN LIU AND BEISHENG KANG Fujian Institute of Research on the Structure of Matter and Fuzhou Laboratory of Structural Chemistry, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China (Received 7 January 1991 ; accepted 23 April 1991) Abstract. Di[bis(diethyldithiocarbamato)(/z-,q2-di- sulfido)vanadium], C2oH4oN4SIEV2, Mr = 823"22, tri- clinic, P1, a= 11.071 (7), b= 12.161 (6), c= 6.714 (4) A, a=102.62(4), fl=95.14(4), y= 97.17(5)°, V=868.8A3, Z=I, Dx=l'57gcm-3 ,~(Mo Ka) 0.71069 A, ~ = 12.4 cm-l, F(000) = 426, room temperature, final R = 0.058 for 1346 unique * To whom correspondence should be addressed. 0108-2701/91 / 102085-03503.00 reflections with (Fo)2 > 3o'(Fo)2. The environment of the V atom in the title compound is of a distorted tetragonal prism geometry. The single V--V bond distance is 2.884 (4)A. Introduction. Vanadium compounds are of