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(plus or minus)-3-Bis(phenylsulfinyl)methyl-1,2-dimethylcyclopropene

(plus or minus)-3-Bis(phenylsulfinyl)methyl-1,2-dimethylcyclopropene


<h2>Acta Crystallographica Section B</h2><h3>Structural Crystallography and Crystal Chemistry</h3><h3>0567-7408</h3> <h2>short structural papers</h2> Volume 35 Part 12 Pages 3119-3122 December 1979 <h2>(±)-3-Bis(phenylsulfinyl)methyl-1,2-dimethylcyclopropene</h2> H. Beckhaus, M. Kimura, W. H. Watson, C. G. Venier and B. Kojic-Prodic Acta Cryst. (1979). B35, 3119-3122 (+)-3-Bis(phenylsulfinyl)methyl- 1,2-dimethylcyclopropene BY HEIKO BECKHAUS, MICHIO KIMURA, WILLIAM H. WATSON, CLIFFORD G. VENIER AND BISERKA KOJIC~-PRODIC* Department of Chemistry, Texas Christian University, Fort Worth, Texas 76129, USA (Received 21 June 1979; accepted 4 September 1979) Abstraet. C18H1802S2, Mr = 330.47, orthorhombic, Pbca, a = 20.711 (9), b = 15.761 (7), c = 10.740 (3) A, V=3506(2) A3,Z=8,dc= 1.252Mgm-3,g= *Current address: lnstitut 'Ruder Bo~kovi6', PO Box 1016, Zagreb, Yugoslavia. 0567-7408/79/123119-04501.00 2.73 mm-~. Full-matrix least-squares refinement (non- hydrogen atoms anisotropic, H atoms isotropic) based on 2535 reflexions led to a final R of 0.078. The geometries around the two S atoms are pyramidal (tetrahedral when the lone pair is considered) and the molecules exhibit R,R and S,S stereochemistries which © 1979 International Union of Crystallography 3120 (+)-3-BIS(PHENYLSULFINYL)METHYL- 1,2-DIMETHYLCYCLOPROPENE is consistent with the diastereoisomeric (+) for- mulation. Introduction. Sulfinyl carbenes are a new and largely unstudied class of organic reactive intermediates (Venier, Barager & Ward, 1975). In a study of their reactions with
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