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P,P-Di-tert-butyl-N-trimethylsilyl-P-(trimethylsilylamino)phosphine imidato-2N,N'bis(pyridine-N)lithium(I)

P,P-Di-tert-butyl-N-trimethylsilyl-P-(trimethylsilylamino)phosphine... In the title compound, Li(C14H36N2PSi2)(C5H5N)2, the bulky chelating monoanionic P,P-di-tert-butyl-N-trimethylsilyl-P-(trimethylsilylamino)phosphine imidate ligand and two pyridine ligands bind to Li in a pseudo-tetrahedral arrangement with twofold symmetry. The Li-Nphosphine distance is 2.048 (5) A, while the LiP distance is 2.520 (6) A. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section C: Crystal Structure Communications International Union of Crystallography

P,P-Di-tert-butyl-N-trimethylsilyl-P-(trimethylsilylamino)phosphine imidato-2N,N'bis(pyridine-N)lithium(I)

P,P-Di-tert-butyl-N-trimethylsilyl-P-(trimethylsilylamino)phosphine imidato-2N,N'bis(pyridine-N)lithium(I)


Abstract

In the title compound, Li(C14H36N2PSi2)(C5H5N)2, the bulky chelating monoanionic P,P-di-tert-butyl-N-trimethylsilyl-P-(trimethylsilylamino)phosphine imidate ligand and two pyridine ligands bind to Li in a pseudo-tetrahedral arrangement with twofold symmetry. The Li-Nphosphine distance is 2.048 (5) A, while the LiP distance is 2.520 (6) A.

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References (9)

Publisher
International Union of Crystallography
Copyright
Copyright (c) 2002 International Union of Crystallography
ISSN
0108-2701
eISSN
1600-5759
DOI
10.1107/S0108270102002706
Publisher site
See Article on Publisher Site

Abstract

In the title compound, Li(C14H36N2PSi2)(C5H5N)2, the bulky chelating monoanionic P,P-di-tert-butyl-N-trimethylsilyl-P-(trimethylsilylamino)phosphine imidate ligand and two pyridine ligands bind to Li in a pseudo-tetrahedral arrangement with twofold symmetry. The Li-Nphosphine distance is 2.048 (5) A, while the LiP distance is 2.520 (6) A.

Journal

Acta Crystallographica Section C: Crystal Structure CommunicationsInternational Union of Crystallography

Published: Mar 21, 2002

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