Orthorhombic crystal form of trans-carbonylchlorobis(triphenylphosphine)rhodium(I) dichloromethane solvate
Abstract
<h2>Acta Crystallographica Section C</h2><h3>Crystal Structure Communications</h3><h3>0108-2701</h3> <h2>short format (metal-organic compounds)</h2> Volume 47 Part 6 Pages 1307-1308 June 1991 <h2>Orthorhombic crystal form of trans -carbonylchlorobis(triphenylphosphine)rhodium(I) dichloromethane solvate</h2> P. A. Chaloner, C. Claver, P. B. Hitchcock, A. M. Masdeu and A. Ruiz Acta Cryst. (1991). C47, 1307-1308 Orthorhombic Crystal Form of trans-Carbonylchlorobis(triphenylphosphine)rhodium(I) Dichloromethane Solvate BY P. A. CHALONER School of Chemistry and Molecular Sciences, University of Sussex, Falmer, Brighton, England C. CLAVER Departament de Quimica, Facultat de Quimica de Tarragona, Pl, Imperial Tarracco 1, 43005 Tarragona, Spain P. B. HITCHCOCK School of Chemistry and Molecular Sciences, University of Sussex, Falmer, Brighton, England AND A. M. MASDEU AND A. RUIZ Departament de Quimica, Facultat de Quimica de Tarragona, Pl, Imperial Tarracco l, 43005 Tarragona, Spain (Received 14 November 1990; accepted 12 December 1990) Abstract. [RhCI(C~8HIsP)2(CO)].CHzC12, Mr = 775.9, orthorhombic, Pbca, a = 23.345 (3), b = 20.644 (7), c = 7.965 (3)/~, V = 3821.9/~3, Z = 4, D.~ = 1-35 g cm-3, monochromated Mo Ka radiation, a = 0-71069 A, /z = 7-6 cm-~, F(000) = 1576, T-- 298 K, R--0.056 and wR--0.063 for 587 observed reflec- tions with IF21 > 3o'(F2). The geometry at Rh is close to square