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fac-Tricarbonylhydroxybis(2-pyridyl)methanolato-3N,O,N'rhenium(I)

fac-Tricarbonylhydroxybis(2-pyridyl)methanolato-3N,O,N'rhenium(I) The ReI centre in the title compound, Re(C11H9N2O2)(CO)3 or fac-Re(CO)3(dpkO,OH) dpkO,OH is hydroxybis(2-pyridyl)methanolato, (I), is in a pseudo-octahedral environment in which the major distortion is due to the constraints associated with the tridentate binding of the dpkO,OH anion. The carbonyl groups are orthogonal, with an average C-Re-C angle of 90.2 (3)Degrees. The molecules pack in stacks of antiparallel tapes of (I) interlocked via a network of hydrogen bonds. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section C: Crystal Structure Communications International Union of Crystallography

fac-Tricarbonylhydroxybis(2-pyridyl)methanolato-3N,O,N'rhenium(I)

fac-Tricarbonylhydroxybis(2-pyridyl)methanolato-3N,O,N'rhenium(I)


Abstract

The ReI centre in the title compound, Re(C11H9N2O2)(CO)3 or fac-Re(CO)3(dpkO,OH) dpkO,OH is hydroxybis(2-pyridyl)methanolato, (I), is in a pseudo-octahedral environment in which the major distortion is due to the constraints associated with the tridentate binding of the dpkO,OH anion. The carbonyl groups are orthogonal, with an average C-Re-C angle of 90.2 (3)Degrees. The molecules pack in stacks of antiparallel tapes of (I) interlocked via a network of hydrogen bonds.

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References (3)

Publisher
International Union of Crystallography
Copyright
Copyright (c) 2002 International Union of Crystallography
ISSN
0108-2701
eISSN
1600-5759
DOI
10.1107/S0108270101019527
Publisher site
See Article on Publisher Site

Abstract

The ReI centre in the title compound, Re(C11H9N2O2)(CO)3 or fac-Re(CO)3(dpkO,OH) dpkO,OH is hydroxybis(2-pyridyl)methanolato, (I), is in a pseudo-octahedral environment in which the major distortion is due to the constraints associated with the tridentate binding of the dpkO,OH anion. The carbonyl groups are orthogonal, with an average C-Re-C angle of 90.2 (3)Degrees. The molecules pack in stacks of antiparallel tapes of (I) interlocked via a network of hydrogen bonds.

Journal

Acta Crystallographica Section C: Crystal Structure CommunicationsInternational Union of Crystallography

Published: Jan 16, 2002

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