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catena-Polycyclo-tetra--chlorotetracopper(I)-bis{-3-(2-morpholino-4-oxo-4,5-dihydro-1,3-thiazol-5-ylidene)methylphenoxypropene}-2N,1'2;12,2'N

catena-Polycyclo-tetra--chlorotetracopper(I)-bis{-3-(2-morpholino-4-oxo-4,5-dihydro-1,3-thiazol-5... Crystals of a new copper(I) complex of composition Cu4Cl4(C17H18N2O3S)2n have been obtained by alternating-current electrochemical synthesis. In the crystal structure, the Cu and Cl atoms form a chair-like Cu4Cl4 cyclic fragment. The organic ligand acts as a bridge, being connected via the C=C bond of the allyl group to a Cu atom from one inorganic cycle and via the N atom of the thiazole ring to a Cu atom of another copper-chloride fragment. The geometry of the center indicates that the Cu-(C=C) interaction is moderately effective. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section C: Crystal Structure Communications International Union of Crystallography

catena-Polycyclo-tetra--chlorotetracopper(I)-bis{-3-(2-morpholino-4-oxo-4,5-dihydro-1,3-thiazol-5-ylidene)methylphenoxypropene}-2N,1'2;12,2'N

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catena-Polycyclo-tetra--chlorotetracopper(I)-bis{-3-(2-morpholino-4-oxo-4,5-dihydro-1,3-thiazol-5-ylidene)methylphenoxypropene}-2N,1'2;12,2'N

Goreshnik, E; Karpyak, V; Mys'kiv, M
Acta Crystallographica Section C: Crystal Structure Communications , Volume 61 (8): m390 – Jul 23, 2005

Abstract

Crystals of a new copper(I) complex of composition Cu4Cl4(C17H18N2O3S)2n have been obtained by alternating-current electrochemical synthesis. In the crystal structure, the Cu and Cl atoms form a chair-like Cu4Cl4 cyclic fragment. The organic ligand acts as a bridge, being connected via the C=C bond of the allyl group to a Cu atom from one inorganic cycle and via the N atom of the thiazole ring to a Cu atom of another copper-chloride fragment. The geometry of the center indicates that the Cu-(C=C) interaction is moderately effective.

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References (8)

Publisher
International Union of Crystallography
Copyright
Copyright (c) 2005 International Union of Crystallography
ISSN
0108-2701
eISSN
1600-5759
DOI
10.1107/S0108270105020299
pmid
16082089
Publisher site
See Article on Publisher Site

Abstract

Crystals of a new copper(I) complex of composition Cu4Cl4(C17H18N2O3S)2n have been obtained by alternating-current electrochemical synthesis. In the crystal structure, the Cu and Cl atoms form a chair-like Cu4Cl4 cyclic fragment. The organic ligand acts as a bridge, being connected via the C=C bond of the allyl group to a Cu atom from one inorganic cycle and via the N atom of the thiazole ring to a Cu atom of another copper-chloride fragment. The geometry of the center indicates that the Cu-(C=C) interaction is moderately effective.

Journal

Acta Crystallographica Section C: Crystal Structure Communications – International Union of Crystallography

Published: Jul 23, 2005

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