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catena-Polybis(ethane-1,2-diammonium) manganese(II)-di--phosphato-4O:O': a one-dimensional manganese phosphate

catena-Polybis(ethane-1,2-diammonium) manganese(II)-di--phosphato-4O:O': a one-dimensional... The title compound, {(C2H10N2)2Mn(PO4)2}n, contains anionic square-twisted chains of formula Mn(PO4)24- constructed from corner-sharing four-membered rings of alternating MnO4 and PO4 units. The Mn and P atoms have distorted tetrahedral coordination and the Mn atom lies on a twofold axis. The linear manganese-phosphate chains are held together by hydrogen-bonding interactions involving the framework O atoms and the H atoms of the ethane-1,2-diammonium cations, which lie in the interchain spaces. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section C Crystal Structure Communications International Union of Crystallography

catena-Polybis(ethane-1,2-diammonium) manganese(II)-di--phosphato-4O:O': a one-dimensional manganese phosphate

catena-Polybis(ethane-1,2-diammonium) manganese(II)-di--phosphato-4O:O': a one-dimensional manganese phosphate


Abstract

The title compound, {(C2H10N2)2Mn(PO4)2}n, contains anionic square-twisted chains of formula Mn(PO4)24- constructed from corner-sharing four-membered rings of alternating MnO4 and PO4 units. The Mn and P atoms have distorted tetrahedral coordination and the Mn atom lies on a twofold axis. The linear manganese-phosphate chains are held together by hydrogen-bonding interactions involving the framework O atoms and the H atoms of the ethane-1,2-diammonium cations, which lie in the interchain spaces.

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References (15)

Publisher
International Union of Crystallography
Copyright
Copyright (c) 2007 International Union of Crystallography
ISSN
0108-2701
eISSN
1600-5759
DOI
10.1107/S0108270107048111
pmid
17989476
Publisher site
See Article on Publisher Site

Abstract

The title compound, {(C2H10N2)2Mn(PO4)2}n, contains anionic square-twisted chains of formula Mn(PO4)24- constructed from corner-sharing four-membered rings of alternating MnO4 and PO4 units. The Mn and P atoms have distorted tetrahedral coordination and the Mn atom lies on a twofold axis. The linear manganese-phosphate chains are held together by hydrogen-bonding interactions involving the framework O atoms and the H atoms of the ethane-1,2-diammonium cations, which lie in the interchain spaces.

Journal

Acta Crystallographica Section C Crystal Structure CommunicationsInternational Union of Crystallography

Published: Oct 24, 2007

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