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Bis(-cyclopentylamino-N:N)dimethylaluminium(III)

Bis(-cyclopentylamino-N:N)dimethylaluminium(III) Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produced the dimeric species bis(-cyclopentylamino-N:N)bisdimethylaluminium(III), Al(CH3)2-(C5H10N)2, which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystallographic symmetry) instead of the more common trans arrangement. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section C: Crystal Structure Communications International Union of Crystallography

Bis(-cyclopentylamino-N:N)dimethylaluminium(III)

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Bis(-cyclopentylamino-N:N)dimethylaluminium(III)

Craig, F.J; Kennedy, A.R; Mulvey, R.E
Acta Crystallographica Section C: Crystal Structure Communications , Volume 56 (1): 31 – Jan 15, 2000

Abstract

Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produced the dimeric species bis(-cyclopentylamino-N:N)bisdimethylaluminium(III), Al(CH3)2-(C5H10N)2, which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystallographic symmetry) instead of the more common trans arrangement.

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References (4)

Publisher
International Union of Crystallography
Copyright
Copyright (c) 2000 International Union of Crystallography
ISSN
0108-2701
eISSN
1600-5759
DOI
10.1107/S0108270199012639
Publisher site
See Article on Publisher Site

Abstract

Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produced the dimeric species bis(-cyclopentylamino-N:N)bisdimethylaluminium(III), Al(CH3)2-(C5H10N)2, which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystallographic symmetry) instead of the more common trans arrangement.

Journal

Acta Crystallographica Section C: Crystal Structure Communications – International Union of Crystallography

Published: Jan 15, 2000

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