Select data courtesy of the U.S. National Library of Medicine.

© 2026 DeepDyve, Inc. All rights reserved.

This site is protected by VikingCloud's Trusted Commerce program

    Aqua(dipicolinato-3O,N,O')(1H-imidazole-N3)(1,10-phenanthroline-N,N')manganese(II)

    Ma, C.-B; Chen, C.-N; Liu, Q.-T
    Acta Crystallographica Section C: Crystal Structure Communications·Sep 29, 2007

    Aqua(dipicolinato-3O,N,O')(1H-imidazole-N3)(1,10-phenanthroline-N,N')manganese(II)

    Abstract

    In the title compound, Mn(C7H3NO4)(C3H4N2)(C12H8N2)(H2O), the MnII centre is surrounded by one bidentate phenanthroline ligand Mn-N = 2.383 (3) and 2.421 (3) A, one tridentate dipicolinate ligand Mn-N = 2.300 (3) A, and Mn-O = 2.300 (2) and 2.357 (2) A, one monodentate imidazole ligand Mn-N = 2.238 (3) A and one water molecule Mn-O = 2.157 (3) A. It displays a distorted pentagonal-bipyramidal geometry, with neighbouring angles within the equatorial plane ranging from 68.05 (9) to 77.48 (10)Degrees. Intermolecular O-HO hydrogen bonds link the molecules into infinite chains. The chains are crosslinked by hydrogen bonds involving the carboxyl O atoms of the dipicolinate ligand and the protonated imidazole N atom, leading to an infinite two-dimensional network sheet packing mode. The complete solid-state structure can be described as a three-dimensional supramolecular framework, stabilized by these intermolecular hydrogen-bonding interactions and - stacking interactions involving the phenanthroline rings.

    Meet DeepDyve

    Get unlimited, instant access to over 150 million full-text scientific articles for less than the price of buying a single PDF.

    150M+Research Papers
    35M+Full-Text Streaming Papers
    25M+Open Access Papers
    $2/dayStarting Price
    DeepDyve Collection

    DeepDyve Collection

    Access top-tier journals without the top-tier price. We partner directly with the world’s leading academic publishers to bring you legally compliant, instant access. Read the latest findings from Springer, Wiley, Oxford University Press, and more—all in one subscription.

    Browse our collection of titles from leading publishers

    arXiv
    ChemRxiv
    Hindawi
    JAMA
    MDPI
    medRxiv
    NEJM
    Oxford University Press
    PLOS
    PubMed
    Sage
    Springer Nature
    Wiley
    Wolters Kluwer
    AI Research Assistant

    AI Research Assistant

    Accelerate your research with our advanced AI tools. Chat directly with your uploaded papers, and DeepDyve’s 50M+ LitStream and OA collections of full-text papers. AI responses come directly from the literature, footnoted and sourced, to provide the most authoritative and verifiable responses. AI outputs powered by OpenAI and Anthropic Claude. AI Smart Folders (coming soon)

    Stop wasting time on paywalls, pirated sites and scattered journal portals

    Streamline your research workflow with DeepDyve's comprehensive literature management solution for less than the price of buying a single PDF.

    Try 1 month for $0