2-n-Propylthiete sulfone
Abstract
<h2>Acta Crystallographica Section C</h2><h3>Crystal Structure Communications</h3><h3>0108-2701</h3> <h2>organic compounds</h2> Volume 50 Part 4 Pages 606-607 April 1994 <h2>2- n -Propylthiete sulfone</h2> G. J. Gainsford and A. D. Woolhouse Acta Cryst. (1994). C50, 606-607 2-n-Propylthiete Sulfone G. J. GAINSFORD AND A. D. WOOLHOUSE The New Zealand Institute for Industrial Research and Development, PO Box 31-310, Lower Hutt, New Zealand (Received 23 March 1993; accepted 20 August 1993) Abstract The title compound, 2-n-propyl-2H-thiete 1,1- dioxide, C6H1002S, was prepared by a Cope elimi- nation from the N-oxide of 3-piperidinyl-2-n- propylthietane sulfone. The molecule has crystallo- graphically imposed mirror symmetry. © 1994 International Union of Crystallography Printed in Great Britain - all rights reserved C(5)t C(3 C(6) C(4 ) J ( o(1) IS(l) o(1)' Fig. 1. An ORTEPII (Johnson, 1971) drawing of 2-n-propylthiete sulfone with 30% probability ellipsoids for non-H atoms. Acta Crystallographica Section C ISSN 0108-2701 ©1994 G. J. GAINSFORD AND A. D. WOOLHOUSE 607 In this first reported thiete sulfone, the different C--S bond lengths are consistent with those found for C(sp2) and C(sp3) atoms (1.819, 1.741 A; Allen et al., 1987) and in substituted thietane dioxides (1.759- 1.844A; Smart & Middleton, 1987, and references therein). Other distances and angles are