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{2-Hydroxy-N'-1-(2-oxidophenyl)ethylidenebenzohydrazidato}morpholinecopper(II)

{2-Hydroxy-N'-1-(2-oxidophenyl)ethylidenebenzohydrazidato}morpholinecopper(II) The CuII ion in the title complex, Cu(C15H12N2O3)(C4H9NO), is coordinated by one carbonyl O atom, one hydrazine N atom and one phenolate O atom from the doubly deprotonated tridentate ligand and one N atom from a morpholine molecule, forming a distorted trans-CuN2O2 square-planar coordination geometry. An intramolecular O-HN hydrogen bond occurs within the ligand, generating an S(6) ring. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section E: Structure Reports Online International Union of Crystallography

{2-Hydroxy-N'-1-(2-oxidophenyl)ethylidenebenzohydrazidato}morpholinecopper(II)

{2-Hydroxy-N'-1-(2-oxidophenyl)ethylidenebenzohydrazidato}morpholinecopper(II)

Acta Crystallographica Section E: Structure Reports Online , Volume 65 (11): m1422 – Oct 23, 2009

Abstract

The CuII ion in the title complex, Cu(C15H12N2O3)(C4H9NO), is coordinated by one carbonyl O atom, one hydrazine N atom and one phenolate O atom from the doubly deprotonated tridentate ligand and one N atom from a morpholine molecule, forming a distorted trans-CuN2O2 square-planar coordination geometry. An intramolecular O-HN hydrogen bond occurs within the ligand, generating an S(6) ring.

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References (12)

Publisher
International Union of Crystallography
Copyright
Copyright (c) 2009 International Union of Crystallography
ISSN
1600-5368
eISSN
1600-5368
DOI
10.1107/S1600536809042810
pmid
21578158
Publisher site
See Article on Publisher Site

Abstract

The CuII ion in the title complex, Cu(C15H12N2O3)(C4H9NO), is coordinated by one carbonyl O atom, one hydrazine N atom and one phenolate O atom from the doubly deprotonated tridentate ligand and one N atom from a morpholine molecule, forming a distorted trans-CuN2O2 square-planar coordination geometry. An intramolecular O-HN hydrogen bond occurs within the ligand, generating an S(6) ring.

Journal

Acta Crystallographica Section E: Structure Reports OnlineInternational Union of Crystallography

Published: Oct 23, 2009

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