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, i.e., rod ‐like helical and disc‐like liquid crystallinity, block copolymer self ‐ assembly , DNA‐like interactions to form an ionic polypeptide–nucleotide complex and packing frustration to construct ...
The self ‐ assembling ability of block copolymers offers an attractive strategy for the organization of π‐conjugated polymers. This article reports the synthesis of a coil – rod – coil triblock copolymer ...
Control over supramolecular architecture is a driving force for the design of structurally novel self ‐ assembling materials such as the rod – coil molecules described here. Composed of a hydrophobic ...
The self ‐ assembly of alternating copolymers (ACPs) has attracted considerable interest due to their unique alternating nature. However, compared with block copolymers , their self ‐ assembly behavior ...
Conjugated rod ‐ coil block copolymers provide an interesting route towards enhancing the properties of the conjugated block due to self ‐ assembly and the interplay of rod ‐ rod and rod ‐ coil interactions ...
for the design of donor‐acceptor rod ‐ coil block copolymers for controlling morphology and physical properties as well as advanced memory device applications. 1. Introduction Self ‐ assembly of block copolymers has ...
new organic optoelectronic devices. The solution self - assembly kinetics of p-conjugated rod - coil block copolymers of symmetric poly(3-hexyl thiophene)-b-poly(2-vinyl pyridine) (P3HT-P2VP) during drying ...
A rod – coil triblock copolymer consisting of a poly(3‐hexylthiophene) (P3HT) rigid block , a styrene coil block , and a coil block with fullerene pendant group has been synthesized (see figure ...
on the macroscopic scale (see picture for AFM images). The tuning of microphase separation and self ‐ organization in block copolymers (BCPs) with π‐conjugated subunits ( rod – coil or rod – rod ) is a promising means ...
blocks , 5a , 7 , 8 the surface pressure, 9 and the concentration of the spreading solution. 8 , 10 Asymmetric diblock copolymers , such as rod – coil molecules consisting of a rigid rodlike segment ...
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