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Solutions of Electrolytes

Solutions of Electrolytes of an appropriate temperature-dependent restriction on the "freely rotating" molecules would help the theory. Mysels (26) finds very little excess turbidity, due to structural hetero­ geneities, above that caused by pressure fluctuations in measurements of light scattering by water. He interprets these results as being inconsistent with a model consisting of "iceberg-like clusters" with "fluid" water mole­ cules in between (27, 28, 29), while they are more nearly consistent with any of the models involving a more homogeneous structure of "honeycomb networks of cages" (20, 25, 29, 30, 31, 32). Choppin & Buijs (33, 34) and Yamatera, Fitzpatrick & Gordon (35) have studied the near infrared spectra of water from the visible to about 1.3 p. as a function of temperature (about 0° to 90°) and of added electrolytes. They interpret the large band between 1.1 and 1.25 p. as the (Vl+V2+V3) band since it has a wavelength intermediate between the corresponding (and more definitively known) bands of the gas (1.136 p.) and solid (1.252 p.). This , STOUGHTON assignm ent is consisten t with that of previous investigators. They (33, 34, 35) assume three different kinds of water molecules and assign bands corre­ sponding to each as http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Annual Review of Physical Chemistry Annual Reviews

Solutions of Electrolytes

Stoughton, R W
Annual Review of Physical Chemistry , Volume 16 (1) – Oct 1, 1965
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Publisher
Annual Reviews
Copyright
Copyright 1965 Annual Reviews. All rights reserved
Subject
Review Articles
ISSN
0066-426X
eISSN
1545-1593
DOI
10.1146/annurev.pc.16.100165.001501
Publisher site
See Article on Publisher Site

Abstract

of an appropriate temperature-dependent restriction on the "freely rotating" molecules would help the theory. Mysels (26) finds very little excess turbidity, due to structural hetero­ geneities, above that caused by pressure fluctuations in measurements of light scattering by water. He interprets these results as being inconsistent with a model consisting of "iceberg-like clusters" with "fluid" water mole­ cules in between (27, 28, 29), while they are more nearly consistent with any of the models involving a more homogeneous structure of "honeycomb networks of cages" (20, 25, 29, 30, 31, 32). Choppin & Buijs (33, 34) and Yamatera, Fitzpatrick & Gordon (35) have studied the near infrared spectra of water from the visible to about 1.3 p. as a function of temperature (about 0° to 90°) and of added electrolytes. They interpret the large band between 1.1 and 1.25 p. as the (Vl+V2+V3) band since it has a wavelength intermediate between the corresponding (and more definitively known) bands of the gas (1.136 p.) and solid (1.252 p.). This , STOUGHTON assignm ent is consisten t with that of previous investigators. They (33, 34, 35) assume three different kinds of water molecules and assign bands corre­ sponding to each as

Journal

Annual Review of Physical Chemistry – Annual Reviews

Published: Oct 1, 1965

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