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Carrier generation mechanisms for photoconductivity in conjugated polymers

Carrier generation mechanisms for photoconductivity in conjugated polymers We study theoretically the origin of photoconductivity in conjugated polymers. The charge carriers are released when excitons dissociate through the deep levels within the semiconductor bandgap caused by either oxidation (carbonyl group) or structure defects. Our results explain the recent observations of the temperature-independent photocurrent in the sweep-out regime and the transient photocurrent at high excitation. The tightly bound exciton versus semiconductor band controversy on the photocarrier generation process is clarified. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Physical Review B American Physical Society (APS)

Carrier generation mechanisms for photoconductivity in conjugated polymers

Physical Review B , Volume 61 (15) – Apr 15, 2000
4 pages

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Publisher
American Physical Society (APS)
Copyright
Copyright © 2000 The American Physical Society
ISSN
1095-3795
DOI
10.1103/PhysRevB.61.9913
Publisher site
See Article on Publisher Site

Abstract

We study theoretically the origin of photoconductivity in conjugated polymers. The charge carriers are released when excitons dissociate through the deep levels within the semiconductor bandgap caused by either oxidation (carbonyl group) or structure defects. Our results explain the recent observations of the temperature-independent photocurrent in the sweep-out regime and the transient photocurrent at high excitation. The tightly bound exciton versus semiconductor band controversy on the photocarrier generation process is clarified.

Journal

Physical Review BAmerican Physical Society (APS)

Published: Apr 15, 2000

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