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neighboring groups , which are common when standard Z‐matrices are used, are avoided. A library of potentially relevant conformers is created with a tool, which we call SSC, denoting Systematic Screening ...
]. However, direct experimental measurements of standard Gibbs energy change of reactions (ΔrG′o) are still limited to ~600 enzymatic reactions cataloged in the Thermodynamics of Enzyme-catalyzed Reactions ...
amounts of water isomers in the sample are characterized by the ortho-to-para ratio (OPR). In thermodynamic equilibrium at high temperature, when many rotational states of water molecules are populated, OPR ...
underinvestigated 3-deazaguanosine (c3G) on RNA properties . We found that these nucleosides can decrease thermodynamic stability of base pairing to a significant extent. The effects are much more pronounced for 3 ...
are generally fairly stable to acids but quite sensitive to alkali (5). Figure 1 Open in new tabDownload slide Chemical structure and property of TCs and their epimers. Figure 1 Open in new tabDownload slide ...
albumin (BSA) was recently discovered. In the present work, the CD-reporting properties of iron(ii) clathrochelates to proteins and the thermodynamic parameters of their binding to albumins are evaluated ...
an average of multiple safranine isomers . In addition to being useful as an electron transfer mediator Safranine has received considerable interest because of its photoreduction properties [9–11]. It has been ...
, unlike the 3′ base of the (6–4) photoproduct (3). This difference affects the thermodynamic properties of the base pair formation and the mutation spectra. While duplexes with guanine opposite the 3 ...
antioxidative properties , but its rate of interaction with free radicals is slower [15]. Tryptophan and its catabolites without aromatic hydroxyl group , such as kynurenine (KYN), KYNA, and anthranilic acid (AA ...
, but it is reasonable to suggest it is the R P isomer because of its retention on a silica gel in analogy with the 2′-deoxy series ( 15 , 16 ). On the other hand, it is possible that the 2′- O -methyl group plays a more ...
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