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Isobutane alkylation over solid acid catalysts under supercritical conditions

Isobutane alkylation over solid acid catalysts under supercritical conditions Solid catalyzed isobutane alkylation has been investigated for decades, but it has not yet been applied in any commercial uses because of the rapid deactivation of the catalyst. Here, the alkylation reaction has been studied under supercritical conditions using metal-promoted and unpromoted sulfated zirconia as catalysts. The catalytic activity at the supercritical condition of 5.0 MPa, 423K was significantly higher than at lower reaction pressure conditions and the deactivation rate was clearly reduced, independent on the catalyst. Iron- and manganese-promoted sulfated zirconia (SFMZ) showed higher activities under all conditions than unpromoted sulfated zirconia (SZ). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Isobutane alkylation over solid acid catalysts under supercritical conditions

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References (15)

Publisher
Springer Journals
Copyright
Copyright © 1998 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
DOI
10.1163/156856798X00492
Publisher site
See Article on Publisher Site

Abstract

Solid catalyzed isobutane alkylation has been investigated for decades, but it has not yet been applied in any commercial uses because of the rapid deactivation of the catalyst. Here, the alkylation reaction has been studied under supercritical conditions using metal-promoted and unpromoted sulfated zirconia as catalysts. The catalytic activity at the supercritical condition of 5.0 MPa, 423K was significantly higher than at lower reaction pressure conditions and the deactivation rate was clearly reduced, independent on the catalyst. Iron- and manganese-promoted sulfated zirconia (SFMZ) showed higher activities under all conditions than unpromoted sulfated zirconia (SZ).

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 14, 2009

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