Access the full text.
Sign up today, get DeepDyve free for 14 days.
R. Parton, I. Vankelecom, Mark Casselman, Cvetana Bezoukhanova, J. Uytterhoeven, P. Jacobs (1994)
An efficient mimic of cytochrome P-450 from a zeolite-encaged iron complex in a polymer membraneNature, 370
T. Tatsumi, Makoto. Nakamura, S. Negishi, H. Tominaga (1990)
Shape-selective oxidation of alkanes with H2O2 catalysed by titanosilicateJournal of The Chemical Society, Chemical Communications
I. Vankelecom, D. Depré, S. Beukelaer, J. Uytterhoeven (1995)
INFLUENCE OF ZEOLITES IN PDMS MEMBRANES - PERVAPORATION OF WATER/ALCOHOL MIXTURESThe Journal of Physical Chemistry, 99
A. Thangaraj, M. Eapen, S. Sivasanker, P. Ratnasamy (1992)
Studies on the synthesis of titanium silicalite, TS-1Zeolites, 12
Z. Gao, Y. Yue, W. Li (1996)
Application of zeolite-filled pervaporation membraneZeolites, 16
I. Vankelecom, E. Scheppers, R. Heus, J. Uytterhoeven (1994)
Parameters Influencing Zeolite Incorporation in PDMS MembranesThe Journal of Physical Chemistry, 98
H. Fu, S. Kaliaguine (1994)
A Kinetic Investigation of Co-Solvent Effects in Oxyfunctionalization of n-Hexane by Hydrogen Peroxide on TS-2Journal of Catalysis, 148
G. Zyl (1959)
Elementary practical organic chemistry. Part 3: quantitative organic analysisJournal of Chemical Education, 36
D. Huybrechts, L. Bruycker, P. Jacobs (1990)
Oxyfunctionalization of alkanes with hydrogen peroxide on titanium silicaliteNature, 345
J. Peureux, M. Torres, H. Mozzanega, A. Giroir‐Fendler, J. Dalmon (1995)
Nitrobenzene liquid-phase hydrogenation in a membrane reactorCatalysis Today, 25
C. Dotremont, B. Brabants, K. Geeroms, J. Mewis, C. Vandecasteele (1995)
Sorption and diffusion of chlorinated hydrocarbons in silicalite-filled PDMS membranesJournal of Membrane Science, 104
J. Armor (1989)
Catalysis with permselective inorganic membranesApplied Catalysis, 49
A. Tuel, Y. Taaˆrit (1994)
Synthesis of titanium silicalite-1 using hexapropyl-1,6-hexanediammonium ions as templating agentZeolites, 14
A. Vaidya, G. Bell, P. Halling (1992)
Aqueous—organic membrane bioreactors. Part I. A guide to membrane selectionJournal of Membrane Science, 71
J. Gallot, H. Fu, M. Kapoor, S. Kaliaguine (1996)
Kinetic Modeling ofn-Hexane Oxyfunctionalization by Hydrogen Peroxide on Titanium Silicalites of MEL Structure (TS-2)Journal of Catalysis, 161
J. Shu, B. Grandjean, A. Neste, S. Kaliaguine (1991)
Catalytic palladium‐based membrane reactors: A reviewCanadian Journal of Chemical Engineering, 69
H. Hsieh (1991)
Inorganic Membrane ReactorsCatalysis Reviews-science and Engineering, 33
In this study, a catalytic membrane reactor was developed. A titanium silicalite (TS-1) containing polydimethylsiloxane (PDMS) catalytic composite membrane was placed at the interface between the two immiscible phases containing respectively n-hexane (organic phase) and a solution of hydrogen peroxide (aqueous phase). This allowed adequate transport of both reactants to the catalyst surface, without using a co-solvent. This concept of zeolite containing catalytic membrane as interphase contactor, which may be applicable to numerous multiphase reactions, has been tested for the oxyfunctionalization of n-hexane to a mixture of hexanols and hexanones using H2O2 as the oxidant. It was shown that the oxyfunctionalization products are formed in and separated by the catalytic membrane. The experimental results illustrated the technical advantages of such a catalytic membrane reactor since the observed conversion and selectivity are similar to the ones obtained with the same catalyst in a conventional reactor. The various factors (membrane thickness, catalyst loading and membrane modifications) which may affect the membrane catalytic and permeation performances were investigated.
Research on Chemical Intermediates – Springer Journals
Published: Apr 15, 2009
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.