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Aromatic substitution in the complexes formed upon addition of gaseous arenium ions to proelectrophiles. A FT-ICR study

Aromatic substitution in the complexes formed upon addition of gaseous arenium ions to... Experiments based on FT-ICR mass spectrometry provide conclusive evidence for the operation of an alternative mechanism of electrophilic aromatic substitution occurring within the complex formed upon addition of gaseous arenium ions to a variety of proelectrophiles, including alkyl halides, alcohols, epoxides, esters and diazoalkanes. The factors affecting the efficiency of the unconventional substitution are examined in the light of the kinetic results of the FT-ICR experiments. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Aromatic substitution in the complexes formed upon addition of gaseous arenium ions to proelectrophiles. A FT-ICR study

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References (11)

Publisher
Springer Journals
Copyright
Copyright
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
DOI
10.1163/156856796X00124
Publisher site
See Article on Publisher Site

Abstract

Experiments based on FT-ICR mass spectrometry provide conclusive evidence for the operation of an alternative mechanism of electrophilic aromatic substitution occurring within the complex formed upon addition of gaseous arenium ions to a variety of proelectrophiles, including alkyl halides, alcohols, epoxides, esters and diazoalkanes. The factors affecting the efficiency of the unconventional substitution are examined in the light of the kinetic results of the FT-ICR experiments.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 14, 2009

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