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J. Weeks, G. Meaburn, S. Gordon (1963)
Absorption coefficients of liquid water and aqueous solutions in the far ultraviolet.Radiation research, 19
T. Loegager, K. Sehested (1993)
Formation and decay of peroxynitric acid : a pulse radiolysis studyThe Journal of Physical Chemistry, 97
J. Villadsen, M. Michelsen (1978)
Solution of differential equation models by polynomial approximation
J. Beckman, Tanya Beckman, Jun Chen, P. Marshall, B. Freeman (1990)
Apparent hydroxyl radical production by peroxynitrite: implications for endothelial injury from nitric oxide and superoxide.Proceedings of the National Academy of Sciences of the United States of America, 87
M. Anbar, M. Bambenek, A. Ross (1973)
Selected specific rates of reactions of transients from water in aqueous solution. 1. Hydrated electron
R. Horne (1978)
The Chemistry of Our Environment
M. Symons (1979)
Unstable intermediates. Part 183. An electron spin resonance study of radicals formed in irradiated sodium and potassium nitriteJournal of The Chemical Society-dalton Transactions
G. Stein (1968)
Radiation Chemistry in Aqueous Systems
G. Markovits, S. Schwartz, L. Newman (1981)
Hydrolysis equilibrium of dinitrogen trioxide in dilute acid solutionInorganic Chemistry, 12
M. Grätzel, A. Henglein, S. Taniguchi (1970)
Pulsradiolytische Beobachtungen über die Reduktion des NO3−‐Ions und über Bildung und Zerfall der persalpetrigen Säure in wäßriger Lösung, 74
K. Irgolic, A. Martell (1985)
Environmental inorganic chemistry
N. Getoff, G. Schenck (1968)
PRIMARY PRODUCTS OF LIQUID WATER PHOTOLYSIS AT 1236, 1470 AND 1849 ÅPhotochemistry and Photobiology, 8
E. Hart (1963)
The Hydrated ElectronScience, 146
L. Forni, V. Mora-Arellano, J. Packer, R. Willson (1986)
Nitrogen dioxide and related free radicals: electron-transfer reactions with organic compounds in solutions containing nitrite or nitrateJournal of The Chemical Society-perkin Transactions 1, 17
G. Lammel, D. Perner, P. Warneck (1990)
Decomposition of pernitric acid in aqueous solutionThe Journal of Physical Chemistry, 94
I. Adamczewski (1969)
Ionization, conductivity, and breakdown in dielectric liquids
B. Bielski (1978)
REEVALUATION OF THE SPECTRAL AND KINETIC PROPERTIES OF HO2 AND O2‐ FREE RADICALSPhotochemistry and Photobiology, 28
M. Saran, C. Michel, W. Bors, G. Czapski (1990)
Reaction of NO with O2-. implications for the action of endothelium-derived relaxing factor (EDRF).Free radical research communications, 10 4-5
P. Neta, R. Huie (1986)
Rate constants for reactions of nitrogen oxide (NO3) radicals in aqueous solutionsThe Journal of Physical Chemistry, 90
S. Lun̆ák, P. Sedlák (1992)
Photoinitiated reactions of hydrogen peroxide in the liquid phaseJournal of Photochemistry and Photobiology A-chemistry, 68
W. Prütz (1984)
Tyrosine Oxidation by NO2• in Aqueous SolutionZeitschrift für Naturforschung C, 39
Water homolyses upon vacuum-uv excitation into HO* radicals, hydrogen atoms and with lower efficiency, hydrated electrons. These primary species induce a series of reactions partially depleting nitrate and nitrite from aqueous solutions. Depletion rates depend on the presence of dissolved oxygen and temperature. Nitrate, nitrite, peroxynitrite and N2O were identified as reaction products after irradiation of, either, nitrite and nitrate in aqueous solutions. A reaction mechanism is proposed in accord with the experimental facts and with the evidence given in the literature, where NO2 * and NO* are key intermediates. NO3 −, NO2 −, NO2 *, NO* O2NO2 −, ONO2 − and N2O, seem to be interrelated by many redox reactions and reaction equilibria where pH and the availability of electrons determine their occurrence. The proposed mechanism is supported by a computer program with which the observed experimental behavior could be simulated.
Research on Chemical Intermediates – Springer Journals
Published: Apr 14, 2009
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