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LASER APPLICATIONS AND OTHER TOPICS IN QUANTUM ELECTRONICS: Study of the kinetics and quantum efficiencies in the photochemistry of provitamin D using a tunable laser
- Publisher
- Springer Journals
- Copyright
- Copyright
- Subject
- Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
- ISSN
- 0922-6168
- eISSN
- 1568-5675
- DOI
- 10.1163/156856795X00495
- Publisher site
- See Article on Publisher Site
Abstract
The possibility of conformational control realization in the reaction of previtamin D photosynthesis in vitro was examined. The sharp changes in the kinetics of provitamin D photoisomerization in some heterogeneous media were attributed to the removal of previtamin D conformational equilibrium by the restriction of its intramolecular rotation. It was found that the quantitative evaluation of the reaction medium effect on the specific previtamin D reaction channels requires consideration of the irreversible photoconversions.
Journal
Research on Chemical Intermediates – Springer Journals
Published: Mar 16, 2009