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R. Atkinson (1991)
Kinetics and Mechanisms of the Gas‐Phase Reactions of the NO3 Radical with Organic CompoundsJournal of Physical and Chemical Reference Data, 20
R. Evans, D. Tingey, M. Gumpertz, W. Burns (1982)
Estimates of Isoprene and Monoterpene Emission Rates in PlantsBotanical Gazette, 143
I. Barnes, V. Bastian, K. Becker, Zhu Tong (1990)
Kinetics and products of the reactions of nitrate radical with monoalkenes, dialkenes, and monoterpenesThe Journal of Physical Chemistry, 94
A. Guenther, R. Monson, R. Fall (1991)
Isoprene and monoterpene emission rate variability: Observations with Eucalyptus and emission rate algorithm developmentJournal of Geophysical Research, 96
C. Greene, R. Atkinson (1992)
Rate constants for the gas‐phase reactions of O3 with a series of alkenes at 296 ± 2 KInternational Journal of Chemical Kinetics, 24
J. Tumlinson, W. Lewis, L. Vet (1993)
HOW PARASITIC WASPS FIND THEIR HOSTSScientific American, 268
S. Paulson, R. Flagan, J. Seinfeld (1992)
Atmospheric photooxidation of isoprene part II: The ozone‐isoprene reactionInternational Journal of Chemical Kinetics, 24
R. Martinez, J. Herron (1988)
Stopped-flow studies of the mechanisms of ozone-alkene reactions in the gas phase: trans-2-buteneThe Journal of Physical Chemistry, 92
R. Atkinson, S. Aschmann, J. Arey, Basima Shorees (1992)
Formation of OH radicals in the gas phase reactions of O3 with a series of terpenesJournal of Geophysical Research, 97
E. Tuazon, R. Atkinson (1990)
A product study of the gas-phase reaction of Isoprene with the OH radical in the presence of NOxInternational Journal of Chemical Kinetics, 22
R. Kamens, M. Gery, H. Jeffries, Maurice Jackson, Ed Cole (1982)
Ozone–isoprene reactions: Product formation and aerosol potentialInternational Journal of Chemical Kinetics, 14
R. Atkinson, D. Baulch, R. Cox, R. Hampson, J. Kerr, J. Troe (1992)
Evaluated kinetic and photochemical data for atmospheric chemistry: Supplement IV: IUPAC subcommittee on gas kinetic data evaluation for atmospheric chemistryAtmospheric Environment. Part A. General Topics, 26
S. Paulson, R. Flagan, J. Seinfeld (1992)
Atmospheric photooxidation of isoprene part I: The hydroxyl radical and ground state atomic oxygen reactionsInternational Journal of Chemical Kinetics, 24
J. Arey, A. Winer, R. Atkinson, S. Aschmann, W. Long, C. Morrison (1991)
The emission of (Z)-3-hexen-1-ol, (Z)-3-hexenylacetate and other oxygenated hydrocarbons from agricultural plant speciesAtmospheric Environment. Part A. General Topics, 25
B. Lamb, A. Guenther, H. Westberg (1987)
A national inventory of biogenic hydrocarbon emissionsAtmospheric Environment, 21
H. Skov, J. Hjorth, C. Lohse, N. Jensen, G. Restelli (1992)
Products and mechanisms of the reactions of the nitrate radical (NO3) with isoprene, 1,3-butadiene and 2,3-dimethyl-1,3-butadiene in airAtmospheric Environment. Part A. General Topics, 26
Stephanie Corchnoy, R. Atkinson (1990)
Kinetics of the gas-phase reactions of hydroxyl and nitrogen oxide (NO3) radicals with 2-carene, 1,8-cineole, p-cymene, and terpinoleneEnvironmental Science & Technology, 24
T. Turlings, J. Tumlinson (1992)
Systemic release of chemical signals by herbivore-injured corn.Proceedings of the National Academy of Sciences of the United States of America, 89 17
D. Tingey, M. Manning, Louis Grothaus, W. Burns (1980)
Influence of light and temperature on monoterpene emission rates from slash pine.Plant physiology, 65 5
D. Tingey, M. Manning, L. Grothaus, W. Burns (1979)
The Influence of Light and Temperature on Isoprene Emission Rates from Live OakPhysiologia Plantarum, 47
J. Arey, A. Winer, R. Atkinson, S. Aschmann, W. Long, C. Morrison, D. Olszyk (1991)
Terpenes emitted from agricultural species found in California's Central ValleyJournal of Geophysical Research, 96
H. Niki, P. Maker, C. Savage, L. Breitenbach, M. Hurley (1987)
FTIR spectroscopic study of the mechanism for the gas-phase reaction between ozone and tetramethylethyleneThe Journal of Physical Chemistry, 91
R. Atkinson, S. Aschmann, W. Carter, A. Winer, J. Pitts (1982)
Alkyl nitrate formation from the NO/sub x/-air photooxidations of C/sub 2/-C/sub 8/ n-alkanesThe Journal of Physical Chemistry
G. Atkinson (1992)
Mechanism by which merging at X lines causes discrete auroral arcsJournal of Geophysical Research, 97
M. Trainer, E. Williams, D. Parrish, M. Buhr, E. Allwine, H. Westberg, F. Fehsenfeld, S. Liu (1987)
Models and observations of the impact of natural hydrocarbons on rural ozoneNature, 329
W. Chameides, R. Lindsay, J. Richardson, CS Kiang (1988)
The role of biogenic hydrocarbons in urban photochemical smog: Atlanta as a case study.Science, 241 4872
J. Treacŷ, M. Hag, Denis O'Farrell, H. Sidebottom (1992)
Reactions of Ozone with Unsaturated Organic Compounds, 96
R. Atkinson, S. Aschmann, E. Tuazon, J. Arey, B. Zielińska (1989)
Formation of 3-Methylfuran from the gas-phase reaction of OH radicals with isoprene and the rate constant for its reaction with the OH radicalInternational Journal of Chemical Kinetics, 21
H. Niki, P. Maker, C. Savage, L. Breitenbach (1983)
Atmospheric ozone-olefin reactions.Environmental science & technology, 17 7
K. Ohta (1984)
Emission of hexenol from higher plantsGeochemical Journal, 18
R. Cvetanovic, D. Singleton (1985)
Reaction of oxygen atoms with olefinsReviews of Chemical Intermediates, 5
K. Lohmann (1992)
How Sea Turtles NavigateScientific American, 266
D. Jacob, S. Wofsy (1988)
Photochemistry of biogenic emissions over the Amazon forestJournal of Geophysical Research, 93
R. Atkinson, S. Aschmann (1993)
Hydroxyl radical production from the gas-phase reactions of ozone with a series of alkenes under atmospheric conditionsEnvironmental Science & Technology, 27
R. Rasmussen (1972)
What do the hydrocarbons from trees contribute to air pollution?Journal of the Air Pollution Control Association, 22 7
J. Arey, Stephanie Corchnoy, R. Atkinson (1991)
Emission of linalool from Valencia orange blossoms and its observation in ambient airAtmospheric Environment. Part A. General Topics, 25
J. Herron (1988)
Evaluated Chemical Kinetic Data for the Reactions of Atomic Oxygen O(3P) with Saturated Organic Compounds in the Gas PhaseJournal of Physical and Chemical Reference Data, 17
B. Lamb, H. Westberg, G. Allwine, Tim Quarles (1985)
Biogenic hydrocarbon emissions from deciduous and coniferous trees in the United StatesJournal of Geophysical Research, 90
V. Isidorov, I. Zenkevich, B. Ioffe (1985)
Volatile organic compounds in the atmosphere of forestsAtmospheric Environment, 19
Stephanie Corchnoy, J. Arey, R. Atkinson (1992)
Hydrocarbon emissions from twelve urban shade trees of the Los Angeles, California, Air BasinAtmospheric Environment. Part B. Urban Atmosphere, 26
M. Trainer, E. Hsie, S. Mckeen, R. Tallamraju, D. Parrish, F. Fehsenfeld, S. Liu (1987)
Impact of natural hydrocarbons on hydroxyl and peroxy radicals at a remote siteJournal of Geophysical Research, 92
J. Logan, M. Prather, S. Wofsy, M. McElroy (1981)
Tropospheric chemistry: A global perspectiveJournal of Geophysical Research, 86
M. Gijzen, E. Lewinsohn, T. Savage, R. Croteau (1993)
Conifer Monoterpenes: Biochemistry and Bark Beetle Chemical Ecology
The formation yields of 1,2-epoxy-2-methyl-3-butene and 1,2-epoxy-3-methyl-3-butene have been measured from the reaction of O3 with isoprene at room temperature and one atmosphere total pressure of N2 and air diluents, with and without cyclohexane to scavenge the OH radicals formed in this reaction system. In addition, a relative rate method was used to determine a rate constant for the gas-phase reaction of O3 with 1,2-epoxy-2-methyl-3-butene of (2.5 ± 0.7) x 10-18 cm3 molecules-1 s-1 at 296 ± 2 K. Our data show that the epoxide yields in N2 and air diluents are the same, with formation yields of 1,2-epoxy-2-methyl-3-butene of 0.028 ± 0.007 and of 1,2-epoxy-3-methyl-3-butene of 0.011 ± 0.004. These data further show that the epoxides arise from the primary O3 reaction with isoprene, and not via the formation of O(3P) atoms from the O3 - isoprene reaction followed by reaction of these O(3P) atoms with isoprene.
Research on Chemical Intermediates – Springer Journals
Published: Mar 16, 2009
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