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Electron spin resonance of radical cations in nafion membranes

Electron spin resonance of radical cations in nafion membranes Studies of radical cations in solution at room temperature are still relatively rare and require very strongly acidic media; we report here the novel use of the superacidic membrane Nafion (having properties similar to trifluoroacetic acid) for the generation and stabilization of several radical cation species. E.s.r. spectroscopy permitted not only the detection and characterization of the radical cation species so generated but also the qualitative comparison of the effects of the semi-rigid membrane environment on radical mobility as compared to that in solution. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Electron spin resonance of radical cations in nafion membranes

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References (15)

Publisher
Springer Journals
Copyright
Copyright © Springer 1989
ISSN
0922-6168
eISSN
1568-5675
DOI
10.1163/156856789x00384
Publisher site
See Article on Publisher Site

Abstract

Studies of radical cations in solution at room temperature are still relatively rare and require very strongly acidic media; we report here the novel use of the superacidic membrane Nafion (having properties similar to trifluoroacetic acid) for the generation and stabilization of several radical cation species. E.s.r. spectroscopy permitted not only the detection and characterization of the radical cation species so generated but also the qualitative comparison of the effects of the semi-rigid membrane environment on radical mobility as compared to that in solution.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Sep 1, 1989

Keywords: Electron Spin Resonance; Radical Cation; Phenazine; NAFION Membrane; Dimethoxybenzene

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