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References (4)
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M. Hatano, K. Otsuka (1989)
The oxidative coupling of methane on lithium nickelate(III)Journal of the Chemical Society, Faraday Transactions, 85
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Tomoyasu Ito, Ji-Xiang Wang, C. Lin, J. Lunsford (1985)
Oxidative dimerization of methane over a lithium-promoted magnesium oxide catalystJournal of the American Chemical Society, 107
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T. Miyazaki, T. Doi, T. Miyamae, I. Matsuura (1997)
Structure and catalysis of LixNi2-xO2 oxide systems for oxidative coupling of methaneStudies in Surface Science and Catalysis, 110
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Selective synthesis of ethylene by partial oxidation of methane over LiCl–Sm2O3Journal of The Chemical Society, Chemical Communications
- Publisher
- Springer Journals
- Copyright
- Copyright © 2002 by VSP 2002
- Subject
- Chemistry; Inorganic Chemistry; Physical Chemistry; Catalysis
- ISSN
- 0922-6168
- eISSN
- 1568-5675
- DOI
- 10.1163/156856702760346897
- Publisher site
- See Article on Publisher Site
Abstract
The mobility of lattice oxygen and the fine structure of LixNi2–xO2 (0 ≤ x ≤ 1.0) were investigated by thermogravimetric analysis and extended X-ray absorption fine structure, respectively. It was proven that the lattice oxygen of LiNiO2 was mobilizable under reductive and oxidative atmosphere at 1033 K. The Ni–O bond lengths in NiO6 slabs markedly changed at around x = 0.65. The results were in good agreement with the dependence of the selectivity for the OCM reaction on LixNi2–xO2 catalysts. It was suggested from these data that the formation of active lattice oxygen species in LiNiO2 should be induced by structural distortion in NiO6.
Journal
Research on Chemical Intermediates – Springer Journals
Published: Oct 13, 2004